H represents hydrogen atom (1
proton/1 electron)
H+1
represents hydrogen ion (1 proton/No electron)
p+1
represents
free proton
We will make no distinction
between H+1 &
p+1
(H+1
actually represents nuclei of 1p, 1p/1n, 1p/2n)
Since it is impossible to have free proton in water,
terms hydronium ion (H3O+1),
hydrogen ion (H+1),
and free proton (p+1)
are often used interchangeably.
Arrhenius Theory
Arrenhius proposed (1883)
that ionic compounds dissociate and can become free ions acting as separate
entities in solution.
ACID: Produces H+1
in Water
BASE: Produces OH-1
in Water
HCl(aq)
H+1
+ Cl-1
HNO3(aq)
H+1
+ NO3-1
NaOH(aq)
Na+1
+ OH-1
NH3(aq)
NH4+1
+ OH-1
(Although NH3 does
not contain OH-1, hydroxide ions form when
added to water)
The Arrhenius theory also allows acid and base to neutralize
each other producing salt & water:
Acid
+ Base
Salt
+ water
H+1(aq)
+ OH-1(aq)
H2O(l)
HCl(aq)
+ NaOH(aq)
NaCl(aq)
+ H2O(l)
Arrenhius theory most limited of the 3 theories; it requires reactions be aqueous and applies only to substances producing H+1,OH-1,or H2O.
Bronsted/Lowry Theory
Bronsted & Lowry proposed a new acid-base theory
in 1923.
ACID: PROTON DONOR
BASE: PROTON ACCEPTOR
When acid transfers proton it becomes conjugate base
(CB); when base accepts proton it becomes conjugate acid (CA). (See
Conjugate Acid/Conjugate Base)
Since protons are always transferred in the Arrenhius
theory, all Arrhenius acid/base reactions are also Bronsted-Lowry
acid/base reactions.
Bronsted-Lowry theory expands
Arrenhius theory to include any proton transfer (water not required).
Lewis Theory
In 1938 Gilbert Lewis proposed a more general acid base
theory.
ACID: Accepts
pair of electrons for sharing
BASE: Donates pair of
electrons for sharing
The product of Lewis acid-base reaction referred to as
adduct. The proton itself can act as Lewis acid. Lewis
expands acid/base reactions to include many substances without H in formula.
F3B+:NH3
F3B:NH3Explained
by Lewis but not Arrenhius or BL
acid
base
adduct
:NH3
Base
because of lone pair
F3B
Acid because of empty orbital